本文主要研究内容
作者（2019）在《Facile synthesis of flake-like dihydrate zinc oxalate particles》一文中研究指出：Monodispersed dihydrated zinc oxalate（ZnC2O4·2H2O） particles with characteristic morphology were synthesized by aging a mixed solution of zinc nitrate（Zn（NO3）2） and sodium oxalate（Na2C2O4） in the presence of a citrate ligand, with an average flat size of approximately 10–15 μm. The important parameters, including the solution pH values and the concentration of the zinc ions and citrate ligand, were investigated using a series of experiments. It is verified that the citrate ligand significantly affects the morphology of zinc oxalate particles, probably via its multiple roles of chelating, dispersing, and selective absorption. Thermodynamic equilibrium of the distribution of zinc species in an aqueous solution of Zn（Ⅱ）-citrate-oxalate-H2O was estimated to explain the experimental results and to clarify the size and morphological evolution mechanism of the precipitated particles.
Abstract
Monodispersed dihydrated zinc oxalate（ZnC2O4·2H2O） particles with characteristic morphology were synthesized by aging a mixed solution of zinc nitrate（Zn（NO3）2） and sodium oxalate（Na2C2O4） in the presence of a citrate ligand, with an average flat size of approximately 10–15 μm. The important parameters, including the solution pH values and the concentration of the zinc ions and citrate ligand, were investigated using a series of experiments. It is verified that the citrate ligand significantly affects the morphology of zinc oxalate particles, probably via its multiple roles of chelating, dispersing, and selective absorption. Thermodynamic equilibrium of the distribution of zinc species in an aqueous solution of Zn（Ⅱ）-citrate-oxalate-H2O was estimated to explain the experimental results and to clarify the size and morphological evolution mechanism of the precipitated particles.
论文参考文献
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：Facile synthesis of flake-like dihydrate zinc oxalate particles论文
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